In situ observation of reductive deposition of uranium on an electrode/electrolyte interface by optical waveguide spectroscopy

Nankawa, Takuya ; Suzuki, Yoshinori; Onuki, Toshihiko

We report the first in situ and real-time observation of UV-vis absorption spectra of uranium electrodeposited on indium-tin-oxide electrodes by slab optical waveguide spectroscopy. An absorption peak around 670 nm was distinguished after a 30-min holding period at -0.2 V (vs. Ag/AgCl). X-ray absorption near edge structure spectroscopy confirmed the presence of uranium(IV) in the uranium electrodeposited on the ITO electrode.

Language	:	English
Journal	:	Chemistry Letters
Volume	:	38
Number	:	11
Pages	:	p.1090 - 1091
Publication Year/Month	:	2009/11
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Paper URL	:	https://doi.org/10.1246/cl.2009.1090
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Keywords	:	no keyword
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Registration No. : AA20090545
JAEA Abstracts No. : 38000027
Paper Submission No. : 6609

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