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Local structure of triangular-lattice oxides LuFeMO$$_{4}$$(M=Co,Cu)

Matsuo, Yoji*; Mori, Shigeo*; Yoshii, Kenji  ; Hayakawa, Hironori*; Ikeda, Naoshi*

We have investigated the local structure of LuFe(Co,Cu)O$$_{4}$$, in which half of Fe ions are replaced by Co and Cu in electronic ferroelectric LuFe$$_{2}$$O$$_{4}$$. It was found that the electron diffraction patterns at room temperature showed diffuse scattering besides fundamental spots. Based on calculations for possible model structures, we suggest the existence of 4-point clusters consisting of Fe and Co/Cu, which is likely the origin of dielectric constant of 10-1000 at room temperature.

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