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Enhancement of carbon diffusion caused by thermal oxidation on Si$$_{1-x}$$C$$_{x}$$ alloy layer/Si(001) surfaces

Hozumi, Hideaki*; Ogawa, Shuichi*; Yoshigoe, Akitaka ; Ishizuka, Shinji*; Harries, J.; Teraoka, Yuden; Takakuwa, Yuji*

In this study, to clarify the behavior of C on the basis of the oxidation kinetics, the oxidation kinetics of an Si$$_{1-x}$$C$$_{x}$$ alloy layer was investigated by real-time photoelectron spectroscopy. The Si$$_{1-x}$$C$$_{x}$$ alloy layer was formed by exposing an Si(001) surface to ethylene (C$$_{2}$$H$$_{4}$$). Although the solubility of C in an Si bulk is as small as about 3.5 $$times$$ 10$$^{17}$$ cm$$^{-3}$$, it is reported that the solubility of C can be increased by about 10$$^{4}$$ times due to the dimerization-induced strain. This makes it possible to form an Si$$_{1-x}$$C$$_{x}$$ alloy layer on the Si(001) surface with x up to 0.2 but within only the first several Si layers. From a comparison between the changes in the depth profile of C and oxygen uptake, the enhancement of C diffusion is considered in terms of the oxidation-induced strain.

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