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Redox-dependant sulphate coordination of neptunium in aqueous solutions

Hennig, C.*; Ikeda, Atsushi  ; Tsushima, Satoru*; Scheinost, A. C.*

The sulphate coordination to neptunium ion has been investigated in aqueous solution by X-ray absorption spectroscopy. The results suggest that the coordination mode of sulphate ion strongly depends the oxidation state of neptunium, and changes from uni- to bidentate modes.

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