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Effect of cation-ordering on thermoelectric properties in layered cobaltates

Igarashi, Dai*; Miyazaki, Yuzuru*; Yubuta, Kunio*; Igawa, Naoki ; Kajitani, Tsuyoshi*

Layered cobaltates ${it A$_{x}$}$CoO$$_{2}$$ (A = Na, Ca, Sr, Ba) were prepared, and those cation orderings on thermoelectric properties were investigated. It was appeared that those samples had a (3+1) dimensional complexed crystal structure with the cation-disordering on the A layer to the Co$$_{2}$$ layer.

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