Double-pulse LIBS of gadolinium oxide ablated by femto- and nano-second laser pulses

Oba, Masaki ; Maruyama, Yoichiro; Akaoka, Katsuaki ; Miyabe, Masabumi   ; Wakaida, Ikuo  

Emission characteristics of gadolinium (Gd) oxide are studied, using ns and fs laser pulses for ablation in double-pulse laser induced breakdown spectroscopy (LIBS). In the current conditions of pulse energy and signal detection timing, emission intensity enhancement in the reheating mode is 25-fold, but the little effect can be observed in a pre-pulse mode. It is shown that the optimum focus position of the ablation pulse is about 5 mm apart from the sample surface in the reheating mode. Although little emission can be observed in single-pulse configuration with fs ablation pulses, the intense emission can be observed in the reheating mode in the double-pulse configuration.