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Soft X-ray natural circular dichroism of aspartic acid and tyrosine

Izumi, Yudai*; Tanabe, Maiko*; Imazu, Akiko*; Mimoto, Aki*; Nakagawa, Kazumichi*; Tanaka, Masahito*; Agui, Akane; Muro, Takayuki*

We measured soft X-ray natural circular dichroism (SXNCD) of aspartic acid (Asp) and tyrosine (Tyr) at oxygen K-edge region, in an attempt to obtain chiral structure at the vicinity of oxygen atoms. SXNCD measurement was carried out at the BL25SU beamline of the SPring-8, Japan. We focused on oxygen COO$$^{-}$$ 1s $$pi$$$$^{*}$$ transitions around 533 eV. Since we used sublimation films which are randomly oriented samples, we could reject E1E2 mechanism and pick up only E1M1 mechanism.

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