High energy XAFS study of molten DyCl systems

Okamoto, Yoshihiro ; Shiwaku, Hideaki ; Suzuki, Shinichi; Akutsu, Kazuhiro; Kobayashi, Toru ; Yaita, Tsuyoshi; Madden, P. A.*

X-ray absorption fine structure (XAFS) measurement of molten DyCl and mixture with LiCl-KCl eutectic were performed by using Dy K-absorption edge. The local structures of solid and molten DyCl and molten 5%DyCl-(LiCl-KCl eutectic) were almost the same except fluctuation factors such as the Debye-Waller factor. It can be estimated that Dy $^{2+}$ ion generated from the disproportional reaction between Dy $^{3+}$ ion and Dy metal is partially dissolved in the mixture melt.

Language	:	Japanese
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Meeting title	:	第42回溶融塩化学討論会
Held date	:	2010/09
Location (city)	:	函館
Location (country)	:	日本
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Keywords	:	no keyword
Research Facility	:	SPring-8(大型放射光施設)
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Registration No. : BB20101683
JAEA Abstracts No. :
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