Refine your search�ソスF     
Report No.
 - 

Sulfate complexation of element 104, Rf, in H$$_{2}$$SO$$_{4}$$/HNO$$_{3}$$ mixed solution ([H$$^{+}$$] = 1.0 M)

Li, Z.; Toyoshima, Atsushi; Asai, Masato  ; Tsukada, Kazuaki  ; Sato, Tetsuya   ; Sato, Nozomi; Kikuchi, Takahiro; Sch$"a$del, M.*; Nagame, Yuichiro ; Liang, X. H.*; Kasamatsu, Yoshitaka*; Komori, Yukiko*; Oe, Kazuhiro*; Shinohara, Atsushi*; Goto, Shinichi*; Murayama, Hiroshi*; Murakami, Masashi*  ; Kudo, Hisaaki*; Haba, Hiromitsu*; Takeda, Yuki*; Nishikawa, Megumi*; Yokoyama, Akihiko*; Ikarashi, Satoshi*; Sueki, Keisuke*; Akiyama, Kazuhiko*

Cation-exchange behavior of $$^{261}$$Rf (T$$_{1/2}$$ = 78 s) produced in the $$^{248}$$Cm($$^{18}$$O, 5n) reaction was studied on a "one-atom-at-a-time" scale in H$$_{2}$$SO$$_{4}$$ (0.15-0.69 M)/HNO$$_{3}$$ mixed solutions ([H$$^{+}$$] = 1.0 M) using an automated ion-exchange separation apparatus coupled with the detection system for alpha-spectroscopy. It was found that adsorption probability (%ads) of $$^{261}$$Rf on cation-exchange resin decreases with increasing [HSO$$_{4}$$$$^{-}$$], showing a successive formation of its sulfate complexes. Rf exhibited much weaker formation of the complexes than the lighter homologues Zr and Hf, which is qualitatively in good agreement with theoretical calculations including relativistic effects.

Accesses

:

- Accesses

InCites™

:

Altmetrics

:

[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.