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Thermodynamic and static properties of plutonium oxides in magnesia-based inert matrix fuels

Miwa, Shuhei  ; Osaka, Masahiko  

Reduction-oxidation behaviors and oxygen potentials of plutonium oxide in magnesia-based inert matrix fuels were experimentally investigated by thermogravimetry. The reduction and oxidation rates of plutonium oxide in magnesia-based inert matrix fuels were lower than those of plutonium oxide. The oxygen potentials of plutonium oxide-containing magnesia-based inert matrix fuels were lower than those of plutonium oxide near stoichiometry, and became closer to those of plutonium oxide with decreasing oxygen-to-metal ratio. These results indicated that the thermodynamic and static properties of inert matrix fuels could be changed for the better by using the MgO matrix.

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