SO
/HNO
mixed solution ([H
] = 1.0 M)Li, Z.; Toyoshima, Atsushi; Asai, Masato 
; Tsukada, Kazuaki ; Sato, Tetsuya 
; Sato, Nozomi; Sch
del, M.*; Nagame, Yuichiro ; Liang, X. H.*; Kasamatsu, Yoshitaka*; Komori, Yukiko*; Oe, Kazuhiro*; Shinohara, Atsushi*; Goto, Shinichi*; Murayama, Hiroshi*; Murakami, Masashi* ; Kudo, Hisaaki*; Haba, Hiromitsu*; Takeda, Yuki*; Nishikawa, Megumi*; Yokoyama, Akihiko*; Ikarashi, Satoshi*; Sueki, Keisuke*; Akiyama, Kazuhiko*
Cation-exchange behavior of 
Rf (T
= 78 s) produced in the 
Cm(
O,5n) reaction was studied on a "one-atom-at-a-time" scale in 0.15-0.69 M HSO/HNO mixed solutions ([H] = 1.0 M) using an automated ion-exchange separation apparatus coupled with a detection system for alpha-spectroscopy (AIDA). It was found that adsorption probabilities (%ads) of Rf on the cation-exchange resin decrease with increasing [HSO
], showing successive formation of Rf sulfate complexes. Rf exhibits a weaker complex formation than the lighter homologues Zr and Hf.
Language |
: | English |
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Meeting title |
: | 2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010) |
Held date |
: | 2010/12 |
Location (city) |
: | Honolulu |
Location (country) |
: | U.S.A. |
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Keywords |
: | no keyword |
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