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Photoluminescence via two different excited states in a mononuclear europium(III) complex with tetradentate schiff base ligands

Ebato, Shota*; Watanabe, Masayuki   ; Nakajima, Kiyohiko*; Tsuchimoto, Masanobu*

A europium(III) complex with tetradentate Schiff base ligands (C$$_{2}$$H$$_{5}$$)$$_{3}$$NH[Eu(3,5Clsalen)$$_{2}$$] was prepared, and its structure was determined by X-ray crystal structure analysis. The complex has an eight-coordinate mononuclear structure with two Schiff base ligands in a ${it meridional}$ form. The complex displays emission bands resulting from ff transitions by excitation at 357 or 234 nm in acetonitrile.

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Category:Chemistry, Multidisciplinary

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