On-line isothermal gas chromatography of oxychlorides of Db (Z=105) and its homologues Nb and Ta

Sato, Tetsuya ; Tsukada, Kazuaki ; Asai, Masato ; Toyoshima, Atsushi; Sato, Nozomi; Li, Z.; Kikuchi, Takahiro; Kaneya, Yusuke*; Nagame, Yuichiro ; Schdel, M.

We have successfully developed an on-line isothermal gas chromatographic apparatus for the study of gas chemistry of the transactinide elements dubnium (Db, Z = 105). Isothermal gas chromatographic behavior of oxychlorides of Nb and Ta, as the lighter homologues of Db, were observed, and the adsorption enthalpies of the Nb and Ta compounds on a quartz surface were determined. Db was also chemical separated in the similar condition.

Language	:	Japanese
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Meeting title	:	日本化学会第91春季年会(2011)
Held date	:	2011/03
Location (city)	:	横浜
Location (country)	:	日本
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Keywords	:	no keyword
Research Facility	:	タンデム加速器
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Registration No. : BB20103702
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