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Thermodynamic interpretation on solubility of neptunium, technetium, selenium and palladium in nitrate and ammonium solutions

Kitamura, Akira  ; Sasaki, Takayuki*

Thermodynamic interpretation on solubility of neptunium, technetium, selenium and palladium in nitrate and ammonium solutions was performed using the thermodynamic database developed by Japan Atomic Energy Agency (JAEA-TDB). We found that we had to pay special care of redox reactions of nitrogen in thermodynamic calculations. Although solubility data used in the present study were well interpreted using JAEA-TDB, we found that nitrate will affect redox conditions and further experimental studies were required to focus redox behavior of nitrogen.

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