Thermochromic properties of low-melting ionic uranyl isothiocyanate complexes

Aoyagi, Noboru ; Shimojo, Kojiro ; Brooks, N. R.*; Nagaishi, Ryuji ; Naganawa, Hirochika ; Van Hecke, K.*; Van Meervelt, L.*; Binnemans, K.*; Kimura, Takaumi

Temperature-dependent yellow-to-red colour changes of uranylthiocyanate complexes with 1-alkyl-3-methylimidazolium cations have been studied by different spectroscopic methods and this phenomenon is attributed to changes in the local environment of the uranyl ion, including the coordination number, as well as to cation - anion interactions.

Language	:	English
Journal	:	Chemical Communications
Volume	:	47
Number	:	15
Pages	:	p.4490 - 4492
Publication Year/Month	:	2011/04
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Paper URL	:	https://doi.org/10.1039/c0cc05550f
DOI for research data	:
Keywords	:	no keyword
Research Facility	:	第4研究棟
Press Release	:
Article of JAEA R&D Review	:	Discovery of Thermochromic Uranium Complexes; Coodination Chemistry in lonic Liquids Using Time-Resolved Laser-Induced Fluorescence Spectroscopy[/]
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Web of Science® Times Cited Count	:	Times Cited Count： If you would like to get the latest times cited, please access the Web of Science®. http://www.webofknowledge.com/wos
InCites™	:	Percentile:70.65 Category:Chemistry, Multidisciplinary
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Registration No. : AA20110032
JAEA Abstracts No. : 39000805
Paper Submission No. : 9048

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