The Existence of memory effect on hydrogen ordering in ice; The Effect makes ice attractive

Arakawa, Masashi*; Kagi, Hiroyuki; Fernandez-Baca, J. A.*; Chakoumakos, B.*; Fukazawa, Hiroshi

The existence of ferroelectric ice XI with ordered hydrogen in space becomes of interest in astronomy and physical chemistry because of the strong electrostatic force. However, the influence was believed to be limited because it forms at narrow temperature range. From neutron diffraction experiments, we found that small hydrogen-ordered domains exist at significantly higher temperature and the domains induce the growth of "bulk" ice XI. The small ordered domain is named "memory" of hydrogen ordered ice because it is the residual structure of ice XI. Since the memory exists up to at least 111 K, most of ices in the solar system are hydrogen ordered and may have ferroelectricity. The small hydrogen-ordered domains govern the cosmochemical properties of ice and evolution of icy grains in the universe.