SO
/HNO
mixed solutionLi, Z.*; Toyoshima, Atsushi; Asai, Masato 
; Tsukada, Kazuaki ; Sato, Tetsuya 
; Sato, Nozomi; Kikuchi, Takahiro; Nagame, Yuichiro ; Sch
del, M.; Pershina, V.*; Liang, X. H.*; Kasamatsu, Yoshitaka*; Komori, Yukiko*; Oe, Kazuhiro; Shinohara, Atsushi*; Goto, Shinichi*; Murayama, Hiroshi*; Murakami, Masashi* ; Kudo, Hisaaki*; Haba, Hiromitsu*; Takeda, Yuki*; Nishikawa, Megumi*; Yokoyama, Akihiko*; Ikarashi, Satoshi*; Sueki, Keisuke*; Akiyama, Kazuhiko*; Kratz, J. V.*
The cation-exchange behavior of 
Rf (
= 78 s) produced in the 
Cm(
O, 5
) reaction was studied on a one-atom-at-a-time scale in 0.15-0.69 M HSO/HNO mixed solutions ([H
] = 1.0 M) using an automated ion-exchange separation apparatus coupled with the detection system for alpha-spectroscopy (AIDA). It was found that adsorption probabilities (
ads) of Rf on cation-exchange resin decrease with an increase of [HSO
], showing a successive formation of Rf sulfate complexes. Rf exhibits a weaker complex formation tendency compared to the lighter homologues Zr and Hf. This is in good agreement with theoretical predictions including relativistic effects.
Language |
: | English |
|---|---|---|
Journal |
: | |
Volume |
: | 100 |
Number |
: | 3 |
Pages |
: | p.157 - 164 |
Publication Year/Month |
: | 2012/03 |
Paper URL |
: |
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Keywords |
: | no keyword |
Research Facility |
: |
Accesses |
: |
- Accesses |
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InCites™ |
: |
Percentile:69.01 Category:Chemistry, Inorganic & Nuclear |
Altmetrics |
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