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Asynchronous melting of embedded metal nanoparticles and silica matrix for shape elongation induced by swift heavy ion irradiation

Amekura, Hiroshi*; Ishikawa, Norito   ; Okubo, Nariaki   ; Nakayama, Yoshiko*; Mitsuishi, Kazuki*

Although the mechanism of shape-elongation of nanoparticles (NPs) by swift-heavy-ion-irradiation is still under debate, melting and solidification for pico-seconds of NPs by thermal spikes has been proposed as one of the processes involved. Elongation of high melting point (MP) NPs (vanadium, $$T$$$$_{rm MP}^{rm bulk}$$ = 1890 $$^{circ}$$C) and of low MP NPs (zinc, $$T$$$$_{rm MP}^{rm bulk}$$ = 420 $$^{circ}$$C) were compared under irradiation with 200 MeV Xe$$^{14+}$$ ions. Irrespective of the large difference in their MPs, both the V and Zn NPs showed comparable elongation. The insensitivity of elongation to the MP can be explained by the asynchronicity of melting of the silica and the NPs.

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