A Study on the absorption spectra of Br $^{-}$ , Br $_{2}$ $^{-.}$ , Br $_{3}$ $^{-}$ in aqueous solutions at elevated temperatures

Lin, M.; Muroya, Yusa*; Katsumura, Yosuke*; Archirel, P.*; Van-Oanh, N. T.*; Nagaishi, Ryuji ; Kumagai, Yuta ; Mostafavi, M.*

The temperature dependent absorption spectra of Br $^{-}$ , Br $_{2}$ $^{-.}$ and Br $_{3}$ $^{-}$ have been investigated by pulse radiolysis or steady-state irradiation. The spectra of Br $_{2}$ $^{-.}$ and Br $_{3}$ $^{-}$ exhibit almost no shift at the absorption maximum, while that of Br $^{-}$ shows a red-shift with increasing temperature. Quantum chemical calculations have been also performed to unveil the nature of the spectral shift of Br $^{-}$ .

Language	:	English
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Meeting title	:	第54回放射線化学討論会
Held date	:	2011/09
Location (city)	:	茨木
Location (country)	:	日本
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Keywords	:	no keyword
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Cooperating Institute	:	東京大学

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Registration No. : BB20111432
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A Study on the absorption spectra of Br, Br, Br in aqueous solutions at elevated temperatures

A Study on the absorption spectra of Br $^{-}$ , Br $_{2}$ $^{-.}$ , Br $_{3}$ $^{-}$ in aqueous solutions at elevated temperatures