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Collapsing processes of charge ordered structure in charge- and spin- frustrated ferrite YbFe$$_{2}$$O$$_{4}$$

Matsumoto, Keisuke*; Koyama, Tsukasa*; Mori, Shigeo*; Yoshii, Kenji  ; Ikeda, Naoshi*

In order to clarify the stability of charge ordered structure (CO) in charge- and spinfrustrated ferrite YbFe$$_{2}$$O$$_{4}$$, we have investigated changes of the CO structure by partial substitution of Mn$$^{2+}$$ for Fe$$^{2+}$$ in YbFe$$_{2}$$O$$_{4}$$ by a transmission electron microscope (TEM), incombination with conventional dielectric measurement. It is revealed that subtle substitution of Mn$$^{2+}$$ for Fe$$^{2+}$$ in YbFe$$_{2}$$O$$_{4}$$ destroyed drastically the CO structure with the wave vector of q=$$<$$1/3 1/3 1/2$$>$$ and, instead, induced polar clustering structure characterized by honeycomb shaped diffuse scatterings in the reciprocal space. The formation of polar clustering structure should be responsible for the characteristic dielectric dispersion.

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