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Micro-/nanofabrication of cross-linked poly($$_{rm L}$$-lactic acid) using electron beam nanoimprint lithography

Okubo, Satoshi*; Nagasawa, Naotsugu; Kobayashi, Akinobu*; Oyama, Tomoko*; Taguchi, Mitsumasa; Oshima, Akihiro*; Tagawa, Seiichi*; Washio, Masakazu*

Electron beam nanoimprint lithography was proposed for fabricating the micro-/nanostructures of cross-linked poly($$_{rm L}$$-lactic acid) (RX-PLLA). PLLA with triallyl isocyanurate (TAIC) solutions were dropped on the Si-molds fabricated by the conventional EB lithography technique. PLLA/TAIC on Si-molds were imprinted and cross-linked with doses from 10 to 500 kGy at room temperature under vacuum. The micro-/nanostructures of RX-PLLA were successfully obtained with high accuracy. Hence, it was found that the imprinted structures of RX-PLLA (100 kGy irradiation) show low line edge roughness and high thermal durability at 120 $$^{circ}$$C.

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Category:Physics, Applied

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