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Phase-change materials; Vibrational softening upon crystallization and its impact on thermal properties

Matsunaga, Toshiyuki*; Yamada, Noboru*; Kojima, Rie*; Shamoto, Shinichi  ; Sato, Masugu*; Tanida, Hajime*; Uruga, Tomoya*; Kohara, Shinji*; Takata, Masaki*; Zalden, P.*; Bruns, G.*; Sergueev, I.*; Wille, H. C.*; Hermann, R. P.*; Wuttig, M.*

Thermal properties of the amorphous and crystalline state of phase-change materials show remarkable differences such as higher thermal displacements and a more pronounced anharmonic behavior in the crystalline phase. These findings are related to the change of bonding upon crystallization.

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Category:Chemistry, Multidisciplinary

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