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Stress corrosion cracking growth tests of small compact tension specimens with different pre-crack length in high temperature water containing hydrogen peroxide

Nakano, Junichi; Sato, Tomonori  ; Kato, Chiaki   ; Kaji, Yoshiyuki  ; Yamamoto, Masahiro ; Tsukada, Takashi ; Iwata, Yusuke*; Tomota, Yo*

Hydrogen peroxide (H$$_{2}$$O$$_{2}$$) is produced by water radiolysis. To study effects of H$$_{2}$$O$$_{2}$$ environments on SCC behavior of stainless steel, crack growth test was conducted in high temperature water containing H$$_{2}$$O$$_{2}$$. Two types of 0.25T-compact tension (CT) specimens were prepared from thermally sensitized type 304 stainless steel. After fatigue pre-crack length of 4.4-4.8 mm introduction, the pre-crack was shortened to 1.1-1.7 mm. For the CT specimens with long pre-crack length, intergranular SCC (IGSCC) was observed near side grooves. For the CT specimens with shortened pre-crack length, IGSCC area spread to the central region. SCC grew linearly in H$$_{2}$$O$$_{2}$$ environments although SCC growth in O$$_{2}$$ environments branched off. As outer oxide layer on the pre-crack, Fe$$_{3}$$O$$_{4}$$ was observed in O$$_{2}$$ environments. In H$$_{2}$$O$$_{2}$$ environments, it changed from Fe$$_{2}$$O$$_{3}$$ toward the crack tip to Fe$$_{3}$$O$$_{4}$$.

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