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Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

過塩素酸水溶液中の4価セリウムの二核錯体

池田 篤史*  ; 津島 悟*; Hennig, C.*; 矢板 毅; Bernhard, G.*

Ikeda, Atsushi*; Tsushima, Satoru*; Hennig, C.*; Yaita, Tsuyoshi; Bernhard, G.*

Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations. This result will be expected to propose a cogent mechanism for catalytic interaction of oxygen generation from water.

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パーセンタイル:88.57

分野:Chemistry, Inorganic & Nuclear

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