-alkene bearing bisazole component formed by sequential C-H homocoupling and ring-closing metathesis-アルケンBisazole西尾 正太郎*; 染手 隆司*; 杉江 敦司*; 小林 徹 
; 矢板 毅; 森 敦紀*
Nishio, Shotaro*; Somete, Takashi*; Sugie, Atsushi*; Kobayashi, Toru; Yaita, Tsuyoshi; Mori, Atsunori*
Clipping by ring-closing metathesis freezes rotation of a C-C bond to result in forming axial chirality. Treatment of bisbenzimidazole bearing an 
-(3-butenyl) substituent with a Grubbs' catalyst undergoes ring-closing metathesis, in which the stereochemistry of the thus formed olefin was exclusively -form. Analysis by HPLC with a chiral stationary column confirmed clear baseline separation of each enantiomer.
使用言語 |
: | English |
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巻 |
: | 14 |
号 |
: | 10 |
ページ数 |
: | p.2476 - 2479 |
発行年月 |
: | 2012/05 |
キーワード |
: | no keyword |
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Access |
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- Accesses |
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パーセンタイル：61.54 分野：Chemistry, Organic |
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