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低酸素濃度下のベントナイト中における炭素鋼の腐食に及ぼす温度の影響

Effect of temperature on corrosion of carbon steel in bentonite under anaerobic conditions

谷口 直樹 ; 鈴木 宏幸; 川崎 学; 渡邊 正敏; 建石 剛*; 九石 正美

Taniguchi, Naoki; Suzuki, Hiroyuki; Kawasaki, Manabu; Watanabe, Masatoshi; Tateishi, Tsuyoshi*; Sazarashi, Masami

人工海水の飽和したベントナイト中における炭素鋼の浸漬試験を30$$sim$$160$$^{circ}$$Cの範囲で温度をパラメータとして行い、重量法により腐食量を求めた。初期腐食速度は高温ほど大きく、皮膜の保護性は80$$sim$$120$$^{circ}$$Cで最も大きくなることがわかった。また、水素脆化の評価に資するため、試験片中に吸収された水素量(拡散性水素)の測定を行った。その結果、温度が高いほど吸収水素量は小さくなる傾向が認められた。

Immersion tests of carbon steel were carried out in bentonite saturated with synthetic seawater between 30-160 $$^{circ}$$C. The corrosion depth was measured by weight loss of the specimens. The results showed that the initial corrosion rates increased with increasing temperature, and that the most protective corrosion product film was formed at 80-120 $$^{circ}$$C. In order to evaluate the possibility of hydrogen embrittlement, the content of absorbed hydrogen (diffusive hydrogen) in specimens were analyzed. The results showed a tendency of decreasing the content of absorbed hydrogen with increasing temperature.

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