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Electrochemical properties of curium ions in LiCl-KCl eutectic melts

Shibata, Hiroki; Hayashi, Hirokazu; Koyama, Tadafumi*

The electrochemical properties of curium ions in LiCl-KCl eutectic melts were studied in the temperature range from 718 to 823 K. A small electrochemical cell used in the present study was designed for the electrochemical measurement of a small amount (1-20 mg) of the highly radioactive minor actinides contained in molten salts in a hot cell. Our data of apparent standard potentials of Cm$$^{3+}$$/Cm couple are reasonably agreement with Osipenko's data (2011) and are lower than Martinot's data (1975). The validity of the reported apparent standard potentials was discussed.

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