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Electrical resistance measurement techniques for metal hydrides under high-pressure H$$_2$$ conditions & electrical transport and structural properties of FeH$$_x$$

Matsuoka, Takehiro*; Hirao, Naohisa*; Oishi, Yasuo*; Shimizu, Katsuya*; Machida, Akihiko; Aoki, Katsutoshi

We present the newly developed electrical resistance measurement technique for metal hydrides compressed in high-pressure H$$_2$$ and the first successful ${it in-situ}$ simultaneous measurements of electrical resistance and X-ray diffraction of FeH at high pressures and low temperatures. The electrical resistivity $$rho$$ showed a sharp increase with the formation of iron-hydride FeH$$_x$$ ($$xsim1$$) at 3.5 GPa. The $$epsilon$$'-phase of FeH was found to be metallic up to 25.5 GPa. The $$rho$$ vs. $$T$$ curves up to 16.5 GPa approximately follow Fermi-liquid law below 25 K. However, $$T^5$$ was found to be better fitting at 25.5 GPa. This change can be related to the previously reported ferromagnetism collapse at corresponding pressures.

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