Structural changes in surface and bulk LiNiMnO during electrochemical reaction on epitaxial thin-film electrodes characterized by X-ray scattering

X線散乱法を用いたエピタキシャルLiNiMnO膜電極の構造変化に関する研究

坂本 和幸*; 平山 雅章*; 小西 宏明*; 園山 範之*; Dupr, N.*; Guyomard, D.*; 田村 和久   ; 水木 純一郎; 菅野 了次*

Sakamoto, Kazuyuki*; Hirayama, Masaaki*; Konishi, Hiroaki*; Sonoyama, Noriyuki*; Dupr, N.*; Guyomard, D.*; Tamura, Kazuhisa; Mizuki, Junichiro; Kanno, Ryoji*

X線散乱法を用いて、LiNiMnOリチウムイオン電池薄膜電極の電池反応中における表面及びバルクの構造変化を追跡した。その結果、(110)面が露出した電極では、バルク構造の変化が認められたが、(003)面が露出した電極では、電極電位が3-5Vの範囲でリチウムイオンの(デ)インターカレーションが認められたかった。一方で、3Vより負になると、不可逆なインターカレーションが起こることがわかった。

Surface and bulk structural changes of LiNiMnO were investigated during electrochemical reaction using synchrotron X-ray scattering and a restricted reaction plane consisting of two dimensional epitaxial-film electrodes. The changes in bulk structure confirmed lithium diffusion through the (110) surface, which was perpendicular to the two-dimensional (2D) edges of the layered structure. No (de)intercalation reaction was observed through the (003) surface at voltages of 3.0-5.0 V. However, intercalation did proceed through the (003) plane below 3.0 V, indicating unusual three-dimensional (3D) lithium diffusion in the over-lithiated 2D structure. During the electrochemical process, the surface of the electrode showed different structure changes from those of the bulk structure. The reaction echanism of the intercalation electrodes for lithium batteries is discussed on the basis of surface and bulk structural changes.