Refine your search:     
Report No.

Formation of an Fe-H complex anion in YFe$$_{2}$$; Adjustment of imbalanced charge by additional Li as an electron donor

Matsuo, Motoaki*; Saito, Hiroyuki; Machida, Akihiko; Sato, Ryutaro*; Takagi, Shigeyuki*; Miwa, Kazutoshi*; Watanuki, Tetsu; Katayama, Yoshinori; Aoki, Katsutoshi; Orimo, Shinichi*

The novel complex hydride YLiFeH$$_{6}$$ with the Fe-H complex anion ([FeH$$_{6}$$]$$^{4-}$$) was synthesized by hydrogenation of YFe$$_{2}$$ together with additional Li. Li adjusts the original imbalanced charge between Y$$^{3+}$$ and [FeH$$_{6}$$]$$^{4-}$$ by donating an electron to convert into Li$$^{+}$$ during the hydrogenation, resulting in the formation of the well charge-balanced state of Y$$^{3+}$$Li$$^{+}$$[FeH$$_{6}$$]$$^{4-}$$.



- Accesses




Category:Chemistry, Multidisciplinary



[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.