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Formation of an Fe-H complex anion in YFe$$_{2}$$; Adjustment of imbalanced charge by additional Li as an electron donor

Matsuo, Motoaki*; Saito, Hiroyuki; Machida, Akihiko; Sato, Ryutaro*; Takagi, Shigeyuki*; Miwa, Kazutoshi*; Watanuki, Tetsu; Katayama, Yoshinori; Aoki, Katsutoshi; Orimo, Shinichi*

The novel complex hydride YLiFeH$$_{6}$$ with the Fe-H complex anion ([FeH$$_{6}$$]$$^{4-}$$) was synthesized by hydrogenation of YFe$$_{2}$$ together with additional Li. Li adjusts the original imbalanced charge between Y$$^{3+}$$ and [FeH$$_{6}$$]$$^{4-}$$ by donating an electron to convert into Li$$^{+}$$ during the hydrogenation, resulting in the formation of the well charge-balanced state of Y$$^{3+}$$Li$$^{+}$$[FeH$$_{6}$$]$$^{4-}$$.

Language

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English

Journal

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RSC Advances (Internet)

Volume

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3

Number

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4

Pages

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p.1013 - 1016

Publication Year/Month

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2013/01

Meeting title

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Held date

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Location (city)

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Location (country)

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Patent information

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PDF

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Paper URL

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https://doi.org/10.1039/c2ra22497f

DOI for research data

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Keywords

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no keyword

Research Facility

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Press Release

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Article of JAEA R&D Review

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Cooperating Institute

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Accesses

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- Accesses

InCites™

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Percentile:53.62

Category:Chemistry, Multidisciplinary

Altmetrics

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