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Extraction behavior of hexavalent and reduced Mo and W with 4-isopropyltropolone (Hinokitiol)

Miyashita, Sunao; Toyoshima, Atsushi; Oe, Kazuhiro*; Sato, Tetsuya  ; Asai, Masato ; Tsukada, Kazuaki ; Nagame, Yuichiro; Sch$"a$del, M.; Kaneya, Yusuke; Haba, Hiromitsu*; Kanaya, Jumpei*; Huang, M.*; Wada, Ayaka*; Kitayama, Yuta*; Yokoyama, Akihiko*; Kratz, J. V.*; Lerum, H. V.*; Omtvedt, J. P.*

The extraction behavior of hexavalent and reduced Mo and W were investigated when aqueous phase was 0.1 M HCl/0.9 M LiCl solution. The D value of Mo was changed from 10 to 1 when applied potential was near 0 to -0.2 V. On the other hand, the D value of W was not changed at all applied potentials in this experimental condition. Those results indicated that Mo was reduced by FEC, and the extraction behavior of reduced Mo was different from hexavalent Mo. In the case of W, W was not reduced or the D values of reduced W was same as hexavalent W.

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