The Redox potential of mendelevium (Md) determined atom-at-a-time with a flow electrolytic column

Schdel, M.; Toyoshima, Atsushi; Li, Z.*; Asai, Masato ; Sato, Nozomi; Kikuchi, Takahiro; Kaneya, Yusuke; Kitatsuji, Yoshihiro ; Tsukada, Kazuaki ; Nagame, Yuichiro ; Oe, Kazuhiro*; Kasamatsu, Yoshitaka*; Kogama, Yuka*; Shinohara, Atsushi*; Haba, Hiromitsu*; Even, J.*

The redox behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. It was clearly observed that, applying appropriate potentials on the chromatography column, the most stable Md $^{3+}$ is reduced to Md $^{2+}$ . The redox potential of the Md $^{2+}$ = Md $^{3+}$ + e $^{-}$ couple was determined to be -0.16 0.05 V vs. a normal hydrogen electrode.

Language	:	English
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Meeting title	:	9th International Conference on the Chemistry and Physics of the Actinide Elements (ACTINIDES 2013)
Held date	:	2013/07
Location (city)	:	Karlsruhe
Location (country)	:	Germany
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Keywords	:	no keyword
Research Facility	:	タンデム加速器
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Registration No. : BB20131136
JAEA Abstracts No. :
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