Electrochemical behavior of americium in NaCl-2CsCl melt

Hayashi, Hirokazu ; Akabori, Mitsuo; Minato, Kazuo

Electrochemical behavior of Am in NaCl-2CsCl melt at 823 K was investigated by transient electrochemical techniques such as cyclic voltammetry and differential pulse voltammetry. The results show that Am(III) ion is reduced to Am metal by a two-step mechanism via Am(II) ion. Formal standard potential of Am(III)/Am(II) and that of Am(II)/Am(0) redox couples have been determined to be -2.73 and -2.97 V vs Cl/Cl, respectively.

Language	:	English
Journal	:	Journal of Radioanalytical and Nuclear Chemistry
Volume	:	303
Number	:	2
Pages	:	p.1331 - 1334
Publication Year/Month	:	2015/02
Meeting title	:	5th Asia-Pacific Symposium on Radiochemistry (APSORC '13)
Held date	:	2013/09
Location (city)	:	Kanazawa
Location (country)	:	Japan
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Paper URL	:	https://doi.org/10.1007/s10967-014-3471-9
DOI for research data	:
Keywords	:	no keyword
Research Facility	:	BECKY(バックエンド研究施設)
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Article of JAEA R&D Review	:
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Registration No. : BB20131788
JAEA Abstracts No. : 43000378
Paper Submission No. : 15516

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