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Measurement of the Md$$^{3+}$$/Md$$^{2+}$$ reduction potential studied with flow electrolytic chromatography

Toyoshima, Atsushi; Li, Z.*; Asai, Masato  ; Sato, Nozomi; Sato, Tetsuya   ; Kikuchi, Takahiro; Kaneya, Yusuke; Kitatsuji, Yoshihiro  ; Tsukada, Kazuaki  ; Nagame, Yuichiro ; Sch$"a$del, M.; Oe, Kazuhiro*; Kasamatsu, Yoshitaka*; Shinohara, Atsushi*; Haba, Hiromitsu*; Even, J.*

The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By applying appropriate potentials on the chromatography column, the more stable Md$$^{3+}$$ is reduced to Md$$^{2+}$$. The reduction potential of the Md$$^{3+}$$ + e$$^{-}$$ $$rightarrow$$ Md$$^{2+}$$ couple was determined to be -0.16$$pm$$0.05 V vs. a normal hydrogen electrode.

Language

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English

Journal

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Inorganic Chemistry

Volume

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52

Number

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21

Pages

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p.12311 - 12313

Publication Year/Month

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2013/11

Meeting title

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Held date

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Location (city)

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Location (country)

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Patent information

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PDF

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Paper URL

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https://doi.org/10.1021/ic401571h

DOI for research data

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Keywords

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no keyword

Research Facility

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タンデム加速器  

Press Release

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Article of JAEA R&D Review

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Cooperating Institute

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理化学研究所; 大阪大学

Accesses

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- Accesses

InCites™

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Percentile:23.58

Category:Chemistry, Inorganic & Nuclear

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