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Proton-exchange mechanism of specific Cs$$^{+}$$ adsorption $$via$$ lattice defect sites of Prussian blue filled with coordination and crystallization water molecules

Ishizaki, Manabu*; Akiba, Sae*; Otani, Asako*; Hoshi, Yuji*; Ono, Kenta*; Matsuba, Mayu*; Togashi, Takanari*; Kanaizuka, Katsuhiko*; Sakamoto, Masatomi*; Takahashi, Akira*; Kawamoto, Toru*; Tanaka, Hisashi*; Watanabe, Masayuki   ; Arisaka, Makoto ; Nankawa, Takuya ; Kurihara, Masato*

We have revealed the fundamental mechanism of specific Cs$$^{+}$$ adsorption into Prussian blue (PB) in order to develop high-performance PB-based Cs$$^{+}$$ adsorbents in the wake of the Fukushima nuclear accident. We compared two types of PB nanoparticles with formulae of Fe$$^{III}$$$$_{4}$$[Fe$$^{II}$$(CN)$$_{6}$$]3$$cdot$$xH$$_{2}$$O (x = 10-15) (PB-1) and (NH$$_{4}$$)0.70Fe$$^{III}$$1.10[Fe$$^{II}$$(CN)$$_{6}$$]$$cdot$$1.7H$$_{2}$$O (PB-2) with respect to the Cs$$^{+}$$ adsorption ability. The synthesised PB-1, by a common stoichiometric aqueous reaction between 4Fe$$^{3+}$$ and 3[Fe$$^{II}$$(CN)$$_{6}$$]$$^{4-}$$, showed much more efficient Cs$$^{+}$$ adsorption ability than did the commercially available PB-2.

Language

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English

Journal

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Dalton Transactions

Volume

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42

Number

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45

Pages

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p.16049 - 16055

Publication Year/Month

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2013/12

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Paper URL

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https://doi.org/10.1039/c3dt51637g

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Keywords

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福島第一原子力発電所事故; Fukushima Daiichi Nuclear Power Station Accident

Research Facility

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第4研究棟  

Press Release

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Article of JAEA R&D Review

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Cooperating Institute

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産業技術総合研究所

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Percentile:99.53

Category:Chemistry, Inorganic & Nuclear

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