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Report No.

Evaluation of plutonium(IV) extraction rate between nitric acid and tri-$$n$$-butylphosphate solution using a glass chip microchannel

Yamamoto, Masahiko  ; Taguchi, Shigeo ; Sato, Soichi ; Surugaya, Naoki 

The extraction of Pu with tri-$$n$$-butyl phosphate (TBP) is performed using a glass microchip to evaluate the extraction rate. The parallel two-phase laminar flow is constructed in a microchannel by introducing plutonium nitrate solution and TBP diluted with $$n$$-dodecane as aqueous and organic phase, respectively. It was found that extraction ratio of Pu increases with increasing the contact time of two phases. A numerical model based on the diffusion in the microchannel and the reaction at the interface was incorporated to evaluate the extraction rate. The experimental data points were subjected to least-squares fitting and the forward extraction rate of Pu(IV) was determined.



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Category:Chemistry, Analytical



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