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二相ステンレス鋼のすき間腐食成長過程の溶解挙動

Dissolution behavior of duplex stainless steels in crevice corrosion growth step

青木 聡  ; 名田 勇史*; 酒井 潤一*

Aoki, So; Nada, Yushi*; Sakai, Junichi*

本研究は、二相ステンレス鋼のすき間腐食成長時の溶解挙動を明らかにすることを目的とした。二相ステンレス鋼を所定の電位に定電位保持し、すき間腐食を成長させた。一定時間経過後、すき間内の腐食部を観察し、その溶解挙動を解析した。また、in-situ観察によって、すき間腐食成長挙動の経時変化を追った。すき間内の腐食部は、外縁部から中心部へ向かって、すなわち進展先端部から起点部に向かって、不働態保持領域、オーステナイト相優先溶解領域、そして両相溶解領域を経てフェライト相優先溶解領域へと遷移するという、4つの領域に区別でき、この腐食形態を維持しながらすき間外縁部に向かい成長した。このような溶解挙動はすき間腐食が発生した全ての保持電位において同様に観察された。この結果は、すき間内外で形成されるマクロセルとIR dropによって説明できる。

The objective of this study is to clarify dissolution behavior of duplex stainless steels in crevice corrosion growth step. Crevice corrosion grew on the duplex stainless steels by holding potential at various values. After a certain period, dissolution behavior of the crevice corrosion was analyzed based on observation of corroded area. Change in crevice corrosion dissolution behavior with time was also investigated by means of in-situ observation. Four types of dissolution regions could be observed in the corrosion area from outside toward inside direction, i.e. tip of the corroded area toward initiation point, in a crevice; they were passive region, the preferential dissolution region of austenitic phase, both phase dissolution region, and the preferential dissolution region of ferritic phase. The crevice corrosion which maintained that four dissolution regions grew toward the edge of the crevice. This dissolution behavior was given at all the potential where crevice corrosion occurred. The result is described by the micro galvanic cell between inside and outside the crevice consists of IR drop.

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