True Boundary for the formation of homoleptic transition-metal hydride complexes

Takagi, Shigeyuki*; Iijima, Yuki*; Sato, Toyoto*; Saito, Hiroyuki; Ikeda, Kazutaka*; Otomo, Toshiya*; Miwa, Kazutoshi*; Ikeshoji, Tamio*; Aoki, Katsutoshi*; Orimo, Shinichi*

Despite many exploratory studies over the past several decades, the presently known transition metals that form homoleptic transition-metal hydride complexes are limited to the Groups 7-12. Here we present evidence for the formation of Mg $_{3}$ CrH $_{8}$ , containing the first Group 6 hydride complex [CrH $_{7}]$ $^{5-}$ .

Language	:	English
Journal	:	Angewandte Chemie; International Edition
Volume	:	54
Number	:	19
Pages	:	p.5650 - 5653
Publication Year/Month	:	2015/05
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Paper URL	:	https://doi.org/10.1002/anie.201500792
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Keywords	:	水素化物; 錯体; 高温高圧合成
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InCites™	:	Percentile:68.44 Category:Chemistry, Multidisciplinary
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Registration No. : AA20150043
JAEA Abstracts No. : 43001151
Paper Submission No. : 16246

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