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XAFS study on effect of molybdenum addition on photo-induced particle formation of palladium

Saeki, Morihisa; Matsumura, Daiju   ; Yomogida, Takumi   ; Taguchi, Tomitsugu; Tsuji, Takuya  ; Kusano, Shogo*; Miyazaki, Tatsuya*; Takao, Koichiro*; Oba, Hironori  ; Nakashima, Nobuaki*

Recently, we found that photo-induced particle formation of Pd$$^{2+}$$ was promoted by coexistence of molybdenum anion in aqueous solution. In this study, we performed in-situ time-resolved XAFS measurement in the photoreduction of Pd$$^{2+}$$ in presence of various concentration of molybdenum anion. The effect of molybdenum addition on photo-induced particle formation of Pd will be discussed based on the relationship between the photoreduction rate of Pd$$^{2+}$$ and the concentration of molybdenum anion.

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