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Irradiation effect in the fabrication of Er$$_2$$O$$_3$$ film on the sputter-treated Si

Fujita, Masaya*; Asaoka, Hidehito  ; Yamaguchi, Kenji

The ion beam sputter deposition method is capable of fabricating highly-oriented Er$$_2$$O$$_3$$ thin film on crystalline Si substrate at 700 $$^circ$$C, by bombarding Er$$_2$$O$$_3$$ target with O$$_2^+$$ ion beam. However, there always exists silicide phase (ErSi) due to direct reaction between sputtered Er atoms and the Si substrate. In order to find ways to prevent, or slow down the reaction of Si with Er, the dependence of the sputter-etching conditions of the substrate, which are conducted prior to deposition to remove surface impurities, on the film crystalline properties was investigated. In the experiment, two sputter-etching conditions, (a) fluence 3.7$$times$$10$$^{15}$$ ions cm$$^{-2}$$ (normally employed condition) and (b) 3.7$$times$$10$$^{16}$$ ions cm$$^{-2}$$, were employed. The results of the film structure observed by XRD analysis indicated that the silicide phase was present irrespective of the fluence conditions employed.

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