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Initial oxidation behavior of Ni$$_{3}$$Al(210) surface induced by supersonic oxygen molecular beam at room temperature

Xu, Y.*; Demura, Masahiko*; Teraoka, Yuden; Yoshigoe, Akitaka ; Sakurai, Junya*; Hirano, Toshiyuki*

The initial oxidation behavior of a clean Ni$$_{3}$$Al (210) surface was studied at 300 K using a supersonic O$$_{2}$$ molecular beam (O$$_{2}$$ SSMB) having an O$$_{2}$$ translational energy of 2.3 eV, and real-time photoemission spectroscopy performed with high-brilliance synchrotron radiation. The evolution behaviors of the O 1s, Ni 2p, Al 2p, and Ni 3p spectra were examined over time during irradiation with the O$$_{2}$$ SSMB. The spectral analysis revealed that both the Al atoms and the Ni atoms on the surface were oxidized; however, the oxidation of Al progressed much faster than that of Ni.

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