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Chemical redox reaction simulation of metallic ions in nitric acid solution

Igarashi, Takahiro  ; Kato, Chiaki   ; Irisawa, Eriko ; Ueno, Fumiyoshi  

It is known that corrosion rate of stainless steel in nitric acid solution is affected by the valence change of oxidizing metallic ions. In this study, we conducted redox reaction analyses using chemical reaction calculation model to clarify the mechanism of valence change. We obtained that the oxidization of metallic ions in the solution is not only caused by nitrus acid but also nitrogen oxides.

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