• help
  • PC | SP
  • JP | EN
          
Refine your search：     
Report No.
 - 
Clear All
Return to the previous page

Crystal structures and magnetic properties of nickel chain compounds PbM$$_2$$Ni$$_6$$Te$$_3$$O$$_{18}$$ (M = Mn, Cd)

Doi, Yoshihiro*; Suzuki, Ryo*; Hinatsu, Yukio*; Kodama, Katsuaki   ; Igawa, Naoki   

The synthesis, crystal structures, and magnetic properties of the pentanary oxides PbM$$_2$$Ni$$_6$$Te$$_3$$O$$_{18}$$ (M = Mn and Cd) were investigated. These compounds crystallize in a hexagonal structure with space group $$P6_3/m$$, in which the Ni$$^{2+}$$ ions form a zigzag chain along the c axis. From the magnetic susceptibility and specific heat measurements, we found that the PbCd$$_2$$Ni$$_6$$Te$$_3$$O$$_{18}$$ behaves as a low-dimensional magnet due to the intrachain an tiferromagnetic interaction between Ni$$^{2+}$$ ions. Both compounds show a long-range antiferromagnetic ordering at 25.7 K (M = Cd) and 86.0 K (Mn). The magnetic structure of PbMn$$_2$$Ni$$_6$$Te$$_3$$O$$_{18}$$ determined by neutron diffraction measurements is a collinear antiferromagnetic arrangement of Mn$$^{2+}$$ ions in the Mn$$_2$$O$$_9$$ dimeric unit and Ni$$^{2+}$$ ions in the zigzag chain.

Language

 :

English

Journal

 :

Inorganic Chemistry

Volume

 :

54

Number

 :

22

Pages

 :

p.10725 - 10731

Publication Year/Month

 :

2015/11

Meeting title

 :

Held date

 :

Location (city)

 :

Location (country)

 :

Patent information

 :

PDF

 :


Paper URL

 :

https://doi.org/10.1021/acs.inorgchem.5b01619

DOI for research data

 :

Keywords

 :

no keyword

Research Facility

 :

JRR-3M(研究炉3)  

Press Release

 :

Article of JAEA R&D Review

 :

Cooperating Institute

 :

Accesses

 :

- Accesses

InCites™

 :

Percentile:35.49

Category:Chemistry, Inorganic & Nuclear

Altmetrics

 :

[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.

Return to the previous page