Refine your search:     
Report No.
 - 

Synthesis, structure, and pressure-induced polymerization of Li$$_{3}$$Fe(CN)$$_{6}$$ accompanied with enhanced conductivity

Li, K.*; Zheng, H.*; Hattori, Takanori; Sano, Asami; Tulk, C. A.*; Molaison, J.*; Feygenson, M.*; Ivanov, I. N.*; Yang, W.*; Mao, H.-K.*

Pressure-induced polymerization of triple bonds would produce conductive conjugated double bonds. To find a metal cyanide with a low polymerization pressure, anhydrous Li$$_{3}$$Fe(CN)$$_{6}$$ is synthesized and its crystal structure is determined. The irreversible bonding between the CN$$^{-}$$ can be realized by use of the industrial apparatus. The conductivity is enhanced by more than 3 orders of magnitude, which makes the polymerized Li$$_{3}$$Fe(CN)$$_{6}$$ a potential cathode material for rechargeable lithium batteries.

Accesses

:

- Accesses

InCites™

:

Percentile:59.5

Category:Chemistry, Inorganic & Nuclear

Altmetrics

:

[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.