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Synthesis, structure, and pressure-induced polymerization of Li$$_{3}$$Fe(CN)$$_{6}$$ accompanied with enhanced conductivity

Li, K.*; Zheng, H.*; Hattori, Takanori   ; Sano, Asami   ; Tulk, C. A.*; Molaison, J.*; Feygenson, M.*; Ivanov, I. N.*; Yang, W.*; Mao, H.-K.*

Pressure-induced polymerization of triple bonds would produce conductive conjugated double bonds. To find a metal cyanide with a low polymerization pressure, anhydrous Li$$_{3}$$Fe(CN)$$_{6}$$ is synthesized and its crystal structure is determined. The irreversible bonding between the CN$$^{-}$$ can be realized by use of the industrial apparatus. The conductivity is enhanced by more than 3 orders of magnitude, which makes the polymerized Li$$_{3}$$Fe(CN)$$_{6}$$ a potential cathode material for rechargeable lithium batteries.

Language

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English

Journal

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Inorganic Chemistry

Volume

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54

Number

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23

Pages

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p.11276 - 11282

Publication Year/Month

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2015/12

Meeting title

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Held date

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Location (city)

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Location (country)

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Patent information

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PDF

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Paper URL

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https://doi.org/10.1021/acs.inorgchem.5b01851

DOI for research data

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Keywords

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高圧力; 中性子回折実験

Research Facility

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J-PARC物質・生命科学実験施設  

Press Release

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Article of JAEA R&D Review

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Cooperating Institute

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Accesses

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- Accesses

InCites™

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Percentile:25.81

Category:Chemistry, Inorganic & Nuclear

Altmetrics

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