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Discrepancy in the periodic table appears at element 103; The Periodic table of elements might be restructured

Sato, Tetsuya   

The first ionization potential (IP$$_1$$) of element 103, lawrencium (Lr), has been successfully determined for the first time by using a newly developed method based on a surface ionization process. The measured IP$$_1$$ value is 4.96 $$pm$$ 0.08 eV. This value is the smallest among those of actinide elements and is in excellent agreement with the value of 4.963(15) eV predicted by state-of-the-art relativistic calculations also performed in this work. Our results strongly support that the Lr atom has an electronic configuration of [Rn]$$7s^25f^{14}7p_{1/2}$$, which is influenced by strong relativistic effects. The present work opens the way for studies on atomic properties of heavy elements with atomic number $$Z > 100$$. Moreover, the present achievement has triggered a controversy on the position of lutetium (Lu) and Lr in the Periodic Table of Elements.

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