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Report No.

Complex chemistry with complex compounds

Eichler, R.*; Asai, Masato ; Brand, H.*; Chiera, N. M.*; Di Nitto, A.*; Dressler, R.*; D$"u$llmann, Ch. E.*; Even, J.*; Fangli, F.*; Goetz, M.*; Haba, Hiromitsu*; Hartmann, W.*; J$"a$ger, E.*; Kaji, Daiya*; Kanaya, Jumpei*; Kaneya, Yusuke*; Khuyagbaatar, J.*; Kindler, B.*; Komori, Yukiko*; Kraus, B.*; Kratz, J. V.*; Krier, J.*; Kudo, Yuki*; Kurz, N.*; Miyashita, Sunao*; Morimoto, Koji*; Morita, Kosuke*; Murakami, Masashi*; Nagame, Yuichiro; Oe, Kazuhiro*; Piguet, D.*; Sato, Nozomi*; Sato, Tetsuya  ; Steiner, J.*; Steinegger, P.*; Sumita, Takayuki*; Takeyama, Mirei*; Tanaka, Kengo*; Tomitsuka, Tomohiro*; Toyoshima, Atsushi; Tsukada, Kazuaki ; T$"u$rler, A.*; Usoltsev, I.*; Wakabayashi, Yasuo*; Wang, Y.*; Wiehl, N.*; Wittwer, Y.*; Yakushev, A.*; Yamaki, Sayaka*; Yano, Shinya*; Qin, Z.*

In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the productions and investigations of fragile single molecular species of superheavy elements. The latest highlight is the formation of very volatile hexacarbonyl compound of element 106, Sg(CO)$$_{6}$$. Following this success, second-generation experiments were performed to measure the first bond dissociation energy between the central metal atom and the surrounding ligand. The method using a tubular decomposition reactor was developed and successfully applied to short-lived Mo(CO)$$_{6}$$, W(CO)$$_{6}$$, and Sg(CO)$$_{6}$$.



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