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Rust and corrosion mechanism of carbon steel in dilute chloride solution at low dose rates

低線量率条件の希薄塩化物溶液での炭素鋼の錆と腐食挙動

本岡 隆文

Motooka, Takafumi

これまでに、Co-60$$gamma$$線照射下での人工海水中の炭素鋼の腐食試験では100Gy/h以上の吸収線量で腐食速度が向上し、サビの黒色から褐色に変化することを報告している。本研究では、Co-60$$gamma$$線線照射下での炭素鋼の腐食機構を錆の同定結果から検討した。$$gamma$$線は鉄イオンの二価から三価への酸化を促進するので、照射下で形成された錆は高い酸化状態とすることが明らかとなった。

Previous corrosion test of carbon steel in dilute artificial seawater under Co-60 $$gamma$$-ray irradiation has indicated that corrosion rate was enhanced at absorbed dose rates: $$>$$100 Gy/h and rust color was changed from black to dark brown. In the present study, the corrosion mechanism of carbon steel under Co-60 $$gamma$$-ray irradiation was investigated by identification of rust. $$gamma$$ rays enhanced oxidation of iron ions from di-valent to tri-valent. Rust formed under irradiation had higher oxidation state.

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