A Thermodynamic model for ZrO $_{2}$ (am) solubility at 25 $^{circ}$ C in the Ca $^{2+}$ -Na $^{+}$ -H $^{+}$ -Cl $^{-}$ -OH $^{-}$ -H $_{2}$ O system; A Critical review

Rai, D.*; Kitamura, Akira ; Altmaier, M.*; Rosso, K. M.*; Sasaki, Takayuki*; Kobayashi, Taishi*

We have critically reviewed experimental data for Zr hydrolysis constant values for formation of several mononuclear and polynuclear species and a solubility product value for ZrO $_{2}$ (am). We have determined new/revised values for the formation constants of Zr(OH) $_{2}$ $^{2+}$ , Zr(OH) $_{4}$ (aq), Zr(OH) $_{5}$ $^{-}$ , Zr(OH) $_{6}$ $^{2-}$ and Ca $_{3}$ Zr(OH) $_{6}$ $^{4+}$ , and the solubility product for ZrO $_{2}$ (am) after the critical review.

Language	:	English
Journal	:	Journal of Solution Chemistry
Volume	:	47
Number	:	5
Pages	:	p.855 - 891
Publication Year/Month	:	2018/05
Meeting title	:
Held date	:
Location (city)	:
Location (country)	:
Patent information	:
PDF	:
Paper URL	:	https://doi.org/10.1007/s10953-018-0766-4
DOI for research data	:
Keywords	:	Solubility; Amorphous zirconium dioxide; ZrO $_{2}$ (am); solubility product; thermodynamic data; hydrolysis constant
Research Facility	:	ENTRY(地層処分基盤研究施設)
Press Release	:
Article of JAEA R&D Review	:
Cooperating Institute	:	Rai Enviro-Chem

Accesses	:	- Accesses
Web of Science® Times Cited Count	:	Times Cited Count： If you would like to get the latest times cited, please access the Web of Science®. http://www.webofknowledge.com/wos
InCites™	:	Percentile:8.45 Category:Chemistry, Physical
Altmetrics	:

Registration No. : AA20170309
JAEA Abstracts No. : 46000746
Paper Submission No. : 20324

[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.

A Thermodynamic model for ZrO(am) solubility at 25C in the Ca-Na-H-Cl-OH-HO system; A Critical review

A Thermodynamic model for ZrO $_{2}$ (am) solubility at 25 $^{circ}$ C in the Ca $^{2+}$ -Na $^{+}$ -H $^{+}$ -Cl $^{-}$ -OH $^{-}$ -H $_{2}$ O system; A Critical review