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A Thermodynamic model for ZrO$$_{2}$$(am) solubility at 25$$^{circ}$$C in the Ca$$^{2+}$$-Na$$^{+}$$-H$$^{+}$$-Cl$$^{-}$$-OH$$^{-}$$-H$$_{2}$$O system; A Critical review

Rai, D.*; Kitamura, Akira  ; Altmaier, M.*; Rosso, K. M.*; Sasaki, Takayuki*; Kobayashi, Taishi*

We have critically reviewed experimental data for Zr hydrolysis constant values for formation of several mononuclear and polynuclear species and a solubility product value for ZrO$$_{2}$$(am). We have determined new/revised values for the formation constants of Zr(OH)$$_{2}$$$$^{2+}$$, Zr(OH)$$_{4}$$(aq), Zr(OH)$$_{5}$$$$^{-}$$, Zr(OH)$$_{6}$$$$^{2-}$$ and Ca$$_{3}$$Zr(OH)$$_{6}$$$$^{4+}$$, and the solubility product for ZrO$$_{2}$$(am) after the critical review.

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Category:Chemistry, Physical

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