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Comprehensive metal extraction using thiodiglycolamic acid extractant; Effect of soft-donor on extraction

Shimojo, Kojiro   ; Fujiwara, Iori*; Sugita, Tsuyoshi   ; Ueda, Yuki   ; Okamura, Hiroyuki   ; Oshima, Tatsuya*; Baba, Yoshinari*; Naganawa, Hirochika  

We have synthesized a thiodiglycolamic acid type ligand with a soft donor atom as a novel extractant. Extraction behavior of 56 metal ions using this extractant was comprehensively investigated. By comparing the extraction properties of this extractant with those of a diglycolamic acid type ligand with a hard donor atom, the effect of soft-hard property in the ether-site on extraction characteristics was clarified.

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