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Relationship between water resistance and structure of MoO$$_{3}$$-containing iron phosphate glass

Fujisawa, Masaharu*; Takebe, Hiromichi*; Kobayashi, Hidekazu ; Amamoto, Ippei

High level radioactive waste contains a relatively large amount of MoO$$_{3}$$. Mo is known to be a difficult element to incorporate in nuclear waste glass such as borosilicate glasses. On the other hand, phosphate glasses is able to contain MoO$$_{3}$$ over a wide and continuous compositional range. In this study, the effect of MoO$$_{3}$$ addition on properties of iron phosphate glass is studied. The glass transition temperature was evaluated. The immersion tests were performed according to MCC-2 test method due to evaluate the water durability. The additional effects of MoO$$_{3}$$ are discussed in terms of glass structure.

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